Deactivation of copper metal catalysts for methanol. Experiment and modeling article pdf available in international journal of hydrogen energy 3935 october 2014 with 379 reads. Methanol steam reforming also requires relatively low water to carbon molar ratio. Combined steam reforming and partial oxidation of methane to synthesis gas under electrical discharge korada supat and sumaeth chavadej the petroleum and petrochemical college, chulalongkorn university, bangkok 10330, thailand. Review article covering developments in methanol steam reforming in the context of pem fuel cell power systems. Mar 21, 2012 methanol might thus play a key role in the transition toward a future energy scenario, which has to be more and more independent from fossil sources. Final forms of the rate expressions for the overall reactions involved in the process of steam reforming of methanol can be expressed as. In the first part of the plant natural gas is converted into synthesis gas. Study of different designs of methanol steam reformers.
Methanol steam reforming for fuel cell applications. Steam reforming of methanol for fuel cell applications. Parametric study of hydrogen production from ethanol steam. A nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst. Development of a methanol reformer for fuel cell vehicles. Methanol steam reforming for hydrogen generation via conventional and membrane. Developmentcommercialization status of methanol steam reformers.
The reaction is very endothermic and typically occurs in a fixed bed reactor, heated by an open flame furnace with natural gas as the feedstock. Semipassive dmfcs represents a particular class able to combine. Combined steam reforming and partial oxidation of methane to. The top countries of supplier is china, from which the percentage of methanol reforming supply is 95% respectively. Catalytic steam reforming of methanol to produce hydrogen on. Subjects covered include methanol background, use, and production, comparison to. It also makes the steam reforming process of methanol energetically favorable. A new palladiumbased catalyst for methanol steam reforming in. Proven autothermal reforming technology for modern large. Methanol steam reforming for hydrogen production chemical. An efficient technique for improving methanol yield using dual co 2. Methanol steam reforming for hydrogen production request pdf. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. Micromachined methanol steam reforming system as a hydrogen supplier for portable proton exchange membrane fuel cells daeeun parka.
Methanol steam reforming over exhydrotalcite cuznal. In both systems the methanol reformer operates at 250 c and steamtomethanol ratio of 1. Nov 27, 2012 a nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst at 150200 c. Srm is defined as steam reforming of methanol frequently. A study of ethanol and methanol as a fuel for onboard hydrogen generation by steam reforming on copperbased. Steam methane reforming smrbased methanol synthesis plants. A methanol reformer is a device used in chemical engineering, especially in the area of fuel cell technology, which can produce pure hydrogen gas and carbon dioxide by reacting a methanol and water steam mixture. Methanol is considered an attractive raw material due to the high hydrogencarbon ratio 4. Nonsyngas direct steam reforming of methanol to hydrogen. Pdf methanol steam reforming for hydrogen production. A wide variety of methanol reforming options are available to you, there are 180 suppliers who sells methanol reforming on, mainly located in asia. Ethanol contains higher number of hydrogen per molecule as compared to water, methanol and methane. Autothermal reformers atrs combine some of the best features of steam reforming. International journal of hydrogen energy 2015, 40 33, 1046310479.
Compact fuel cell type steam methane reformers with concentric annular. A potential advantage of the membrane microreactor is the fact that both ethanol steam reforming and the separation of hydrogen by a permselective membrane occur in one single microdevice. Methanol steam reforming for hydrogen generation via conventional. The capital cost of large scale methanol plants is substantial. Study on coupling model of methanol steam reforming and. The process layout includes adiabatic prereforming 2, tubular reforming, and oxygenblown secondary reforming. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. Methanol steam reforming for in situ hydrogen production for fuel cell applications has been studied mostly as a standalone process. Methanol steam reforming for hydrogen generation via. The simulation results for steam reforming yields are in agreement with experimental data found in the literature. In contrast, catalyst poisoning and coking have been observed in methanol decomposition and methanol steam reforming reactions. Where, where, the ratedetermining step chosen for both the methanol steam reforming reaction and the decomposition reaction was the dehydrogenation of adsorbed methoxy. Methanol steam reforming in a dual bed membrane reactor for.
The steam reforming of methanol over a cuznoal2o3 catalyst has been investigated. This might mitigate the distribution problems associated with hydrogen. For a comparison, the catalytic performance of sm support was also measured. Methanol steam reforming msr reaction has been seen as a very attractive and.
Steam reforming is the most efficient and popular way of producing hydrogen gas. Pdf hydrogen production by the catalytic steam reforming. In methanol synthesis involving modern promoted cuznoal2 o3 catalysts neither poisoning nor coking is normally a significant source of deactivation. Kinetics, catalysis and mechanism of methane steam reforming. Pdf modeling methanol steam reforming for internal. Catalytic steam reforming of methanol to produce hydrogen. Aug 07, 1990 the production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800 to about 1,100 f. The goal of the reformer is to remove as much of the hydrogen h as possible from this molecule, while minimizing the emission of pollutants such as carbon monoxide co. Steam reforming sr of methanol has been extensively studied in recent years 17. Methanol steam reforming behavior of copper impregnated over ceo 2 zro 2 derived from a surfactant assisted coprecipitation route. Mwcnts as a catalyst in oxysteam reforming of methanol. John bogild hansen haldor topsoe methanol workshop, lund university march 17, 2015. Methanol has a low boiling point, a high hydrogencarbon ratio and no cc bonds, and can therefore be reformed at a relatively low temperature, reducing the risk of coke formation during the reaction.
This chapter focuses mainly on the challenges of catalyst development for methanol steam reforming. Pdf progress in methanol steam reforming modelling via. Generally methanol reforming reaction occurs at comparatively lower temperature 200300c as compared to the temperature 800900c for gasoline reforming. Hydrogen production by the catalytic steam reforming of methanol part 1. Steam reforming and partial oxidation are the two basic types of fuel. The wellknown steam reforming process usually used to extract hydrogen from methanol, called the methanol reformer, traditionally produces carbon. Steam reforming of liquid hydrocarbons is seen as a potential way to provide fuel for fuel cells. The main purpose of this technology is to hydrogen production. There are a couple of types of steam reformers, one reforming methanol and the other reforming natural gas. Stable hydrogen production from ethanol through steam. Advances in methanol production and utilization, with.
Conventional twostep reforming topsoes conventional technology for producing syngas in methanol plants involves the socalled two step reforming concept 1 fig. Pdf in the recent years, hydrogen has gained a considerable interest as an energy. Steam reforming of methanol is endothermic overall i. The basic idea is that for example a methanol tank and a steam reforming unit would replace the bulky pressurized hydrogen tanks that would otherwise be necessary. Modeling methanol steam reforming for internal combustion engine. Using 23wt% cu80zno20cnts as the catalyst, we obtained the hydrogen yield for steam reforming of methanol of 83% at 280c and near 100% at temperatures higher than 320c with 1. C2pt catalyst process technology by gerard b hawkins managing director 2. Nonsyngas direct steam reforming of methanol to hydrogen and. From a technical point of view methanol is the ideal fuel, as it can easily be converted into hydrogen at reasonable temperatures methanol steam reforming and selective co methanation. Methanol steam reformer high temperature pem fuel cell system. Reformers for the production of hydrogen from methanol and. Cuznoal2o3 catalysts have been prepared via hydrotalcitelike hydroxycarbonate precursors and tested in the oxidative steam reforming of methanol mosr to produce hydrogen with poor co content. Methanol steam reforming msr reaction has been seen as a very attractive and promising process for hydrogen production and, according to the scientific literature on the argument, it can be described by the following chemical reactions.
The reaction yields carbon dioxide and hydrogen in the ratio of one to three, with small amounts of dimethyl. Classical pemfc stack operates at 90 c while hightemperature pemfc stack operates at 250 c. Atr combines substoichiometric combustion and catalytic steam reforming in one compact refractory lined reactor to produce synthesis gas for production of more than 10,000 mtpd of methanol. Hydrogen production by steam reforming of ethanol over pt. Pdf methanol steam reforming for hydrogen generation via. Micromachined methanol steam reforming system as a hydrogen. Steam methane reforming is the most common and economical way to make hydrogen. During steam reforming of ethanol, catalyst plays a major role in the productivity and selectivity of generated gas. At present, most of the worlds hydrogen is produced from natural gas 97 % ch4 by a process called steam reforming 38. Implementing glycerol steam reforming will make hydrogen production less dependent on finite fossil fuels 32.
Compact unit in combining both reaction and hydrogen purification with a. Additionally, the system with a classical pemfc stack uses a catalytic burner to supply the endothermal reforming process with sufficient heat. The primary ways in which methane, is converted to hydrogen. Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. Steam reforming of methane produces a mixture of co2, co, and h2. Hydrogen production by steam reforming of ethanol over ptceo 2 catalyst in electric field at low temperature. Review of small stationary reformers for hydrogen production. In describing methanol steam reforming, we have limited our. Steam reforming of methanol for fuel cell grade hydrogen.